yes ,I want to build a Win32 GUI project.
So what I say - choose Win32 application from the wizards. It's even shown on your screenshot on the lower right.
Maybe the OP is really asking if one can
develop an MFC application in C::B [from scratch], as a free alternative to Visual Studio? If that is the real question, I would say it isn't what C::B is meant to do (the way I understand it). But if one is willing to lreplace MFC with wxWidgets, then C::B with wxSmith/wxWidgets is the perfect tool. I would recomend that, coming from MFC myself.