Hi,
I tried to add your lines in my options_gfortran.xml (in my C:\Program Files (x86)\CodeBlocks\share\CodeBlocks\compilers folder).
It works as expected : new options appear in my fortran compiler options.
I had a problem with my 64 bits version because my configuration for gfortran 64 was based on gcc. But, I rebuilt it from standard gfortran, and it also works now.
So, there is something wrong in your configuration, but it should work.
cordially,
gd_on